Modeling eddy transport of passive tracers

The mean advective and eddy transport of a passive scalar property is examined. Using a theory based on rational approximation of Lagrangian particle statistics, a transport equation relating the mean eddy flux and the mean concentration field Θ is developed. The transport equation is an elaborated advection-diffusion model in which the mean eddy flux is determined by the recent history of the gradient of Θ. The flux law involves an eddy diffusivity which depends on time lag and is defined in terms of fluid particle trajectories. Particle trajectories in simulated geophysical turbulence are used to test the applicability of the restrictions upon which the model is based. Examples are given of how Θ fields are affected by the difference between an advection-diffusion model and its elaborated relative

Methods for estimating directional wave spectra from multi-element arrays

1. Introduction The Fourier wavenumber-frequency spectrum of a scalar variable η, with zero mean, is defined

Observations of the power and directional spectrum of ocean surface waves

Estimates of the power spectrum and directional spectrum of oceanic surface waves were obtained from data taken during the Barbados Oceanographic and Meteorological Experiment (BOMEX). Wind speeds ranged from 5 to 10 m s-1 throughout the month\u27s duration of the experiment...

The North Atlantic circulation: Combining simplified dynamics with hydrographic data

We estimate the time-averaged velocity field in the North Atlantic from observations of density, wind stress and bottom topography. The flow is assumed geostrophic, with prescribed Ekman pumping at the surface, and no normal component at the bottom. These data and dynamics determine velocity to within an arbitrary function of (Coriolis parameter)/(ocean depth), which we call the “dynamical free mode.” The free mode is selected to minimize mixing of potential density at mid-depth. This tracer-conservation criterion serves as a relatively weak constraint on the calculation. Estimates of vertical velocity are particularly sensitive to variations in the free mode and to errors in density. In contrast, horizontal velocities are relatively robust. Below the thermocline, we predict a strong O (1 cm/sec) westward flow across the entire North Atlantic, in a narrow range of latitude between 25N and 32N. This feature supports the qualitative (and controversial) conjecture by Wüst (1935) of flow along the “Mediterranean Salt Tongue.” Along continental margins and at the Mid-Atlantic Ridge, predicted bottom velocity points along isobaths, with shallow water to the right. These flows agree with many long-term current measurements and with notions of the circulation based on tracer distributions. The results conflict with previous oceanographic-inverse models, which predict mid-depth flows an order of magnitude smaller and often in opposite directions. These discrepancies may be attributable to our relatively strong enforcement of the bottom boundary condition. This involves the plausible, although tenuous, assertion that the flow “feels” only the large-scale features of the bottom topography. Our objective is to investigate the consequences of using this hypothesis to estimate the North Atlantic circulation

Mesoscale Hydrographic Variability in the Vicinity of Points Conception and Arguello During April May 1983: The OPUS 1983 Experiment

In April and May 1983, interdisciplinary oceanographic observations were made of upwelling events in the Point Conception area off southern California. The principal objective was to observe the structure and time dependence of the upwelling system. To accomplish this, two ships, two aircraft, moorings, drogues, and satellite imagery were all included in the observational effort. During the intensive measurement period three main upwelling events and two intervening relaxation or downwelling intervals were sampled during what was a period of overall longer-term sea surface warming. Surface temperatures during upwelling were as low as 10.5°C in the upwelling center between Point Arguello and Point Conception, while during periods of nonupwelling winds, temperatures reached 14°–15°C in the same area. The upwelling center was also a source of higher-salinity water (33.7‰) relative to the offshore waters that were anomalously fresh (33.3‰). Upwelling was observed off Point Arguello, Point Conception, and the area between with a possible lag of up to a day at Point Conception relative to the other areas. The upwelling plume as observed by surface mapping and remote sensing tended to move in a variety of directions from SE to SW. Part of the movement was usually into the Santa Barbara Channel, but other parts of the plume occasionally moved southwestward. There was no obvious correlation of plume direction with the wind. During relaxation events the entire region was covered by a 10- to 20-m-thick warm (14°–16°C), fresh

Collective motion, sensor networks, and ocean sampling

Author Posting. © IEEE, 2007. This article is posted here by permission of IEEE for personal use, not for redistribution. The definitive version was published in Proceedings of the IEEE 95 (2007): 48-74, doi:10.1109/jproc.2006.887295.This paper addresses the design of mobile sensor networks for optimal data collection. The development is strongly motivated by the application to adaptive ocean sampling for an autonomous ocean observing and prediction system. A performance metric, used to derive optimal paths for the network of mobile sensors, defines the optimal data set as one which minimizes error in a model estimate of the sampled field. Feedback control laws are presented that stably coordinate sensors on structured tracks that have been optimized over a minimal set of parameters. Optimal, closed-loop solutions are computed in a number of low-dimensional cases to illustrate the methodology. Robustness of the performance to the influence of a steady flow field on relatively slow-moving mobile sensors is also explored

Thermohaline structure in the California Current System : observations and modeling of spice variance

Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 117 (2012): C02008, doi:10.1029/2011JC007589.Upper ocean thermohaline structure in the California Current System is investigated using sustained observations from autonomous underwater gliders and a numerical state estimate. Both observations and the state estimate show layers distinguished by the temperature and salinity variability along isopycnals (i.e., spice variance). Mesoscale and submesoscale spice variance is largest in the remnant mixed layer, decreases to a minimum below the pycnocline near 26.3 kg m−3, and then increases again near 26.6 kg m−3. Layers of high (low) meso- and submesoscale spice variance are found on isopycnals where large-scale spice gradients are large (small), consistent with stirring of large-scale gradients to produce smaller scale thermohaline structure. Passive tracer adjoint calculations in the state estimate are used to investigate possible mechanisms for the formation of the layers of spice variance. Layers of high spice variance are found to have distinct origins and to be associated with named water masses; high spice variance water in the remnant mixed layer has northerly origin and is identified as Pacific Subarctic water, while the water in the deeper high spice variance layer has southerly origin and is identified as Equatorial Pacific water. The layer of low spice variance near 26.3 kg m−3 lies between the named water masses and does not have a clear origin. Both effective horizontal diffusivity, κh, and effective diapycnal diffusivity, κv, are elevated relative to the diffusion coefficients set in the numerical simulation, but changes in κh and κv with depth are not sufficient to explain the observed layering of thermohaline structure.We gratefully acknowledge funding from the Gordon and Betty Moore Foundation, the Coastal Ocean Currents Monitoring Project (COCMP), and NOAA. R. E. Todd was partially supported by the Postdoctoral Scholar Program at the Woods Hole Oceanographic Institution, with funding provided by the Cooperative Institute for the North Atlantic Region.2012-08-0

Epidermal Growth Factor–PEG Functionalized PAMAM-Pentaethylenehexamine Dendron for Targeted Gene Delivery Produced by Click Chemistry

Aim of this study was the site-specific conjugation of an epidermal growth factor (EGF)-polyethylene glycol (PEG) chain by click chemistry onto a poly(amido amine) (PAMAM) dendron, as a key step toward defined multifunctional carriers for targeted gene delivery. For this purpose, at first propargyl amine cored PAMAM dendrons with ester ends were synthesized. The chain terminal ester groups were then modified by oligoamines with different secondary amino densities. The oligoamine-modified PAMAM dendrons were well biocompatible, as demonstrated in cytotoxicity assays. Among the different oligoamine-modified dendrons, PAMAM-pentaethylenehexamine (PEHA) dendron polyplexes displayed the best gene transfer ability. Conjugation of PAMAM-PEHA dendron with PEG spacer was conducted via click reaction, which was performed before amidation with PEHA. The resultant PEG-PAMAM-PEHA copolymer was then coupled with EGF ligand. pDNA transfections in HuH-7 hepatocellular carcinoma cells showed a 10-fold higher efficiency with the polyplexes containing conjugated EGF as compared to the ligand-free ones, demonstrating the concept of ligand targeting. Overall gene transfer efficiencies, however, were moderate, suggesting that additional measures for overcoming subsequent intracellular bottlenecks in delivery have to be taken

Averaging in Cosmology

In this paper we discuss the effect of local inhomogeneities on the global expansion of nearly FLRW universes, in a perturbative setting. We derive a generic linearized averaging operation for metric perturbations from basic assumptions, and we explicify the issue of gauge invariance. We derive a gauge invariant expression for the back-reaction of density inhomogeneities on the global expansion of perturbed FLRW spacetimes, in terms of observable quantities, and we calculate the effect quantitatively. Since we do not adopt a comoving gauge, our result incorporates the back-reaction on the metric due to scalar velocity and vorticity perturbations. The results are compared with the results by other authors in this field.Comment: 24 pages, Latex, accepted for publication in Phys. Rev.